Coupling Neural Networks and Physics Equations For Li-Ion Battery State-of-Charge Prediction

Estimating the evolution of the battery's State of Charge (SoC) in response to its usage is critical for implementing effective power management policies and for ultimately improving the system's lifetime. Most existing estimation methods are either physics-based digital twins of the battery or data-driven models such as Neural Networks (NNs). In this work, we propose two new contributions in this domain. First, we introduce a novel NN architecture formed by two cascaded branches: one to predict the current SoC based on sensor readings, and one to estimate the SoC at a future time as a function of the load behavior. Second, we integrate battery dynamics equations into the training of our NN, merging the physics-based and data-driven approaches, to improve the models' generalization over variable prediction horizons. We validate our approach on two publicly accessible datasets, showing that our Physics-Informed Neural Networks (PINNs) outperform purely data-driven ones while also obtaining superior prediction accuracy with a smaller architecture with respect to the state-of-the-art.

Data-Driven Quantification of Battery Degradation Modes via Critical Features from Charging

Battery degradation modes influence the aging behavior of Li-ion batteries, leading to accelerated capacity loss and potential safety issues. Quantifying these aging mechanisms poses challenges for both online and offline diagnostics in charging station applications. Data-driven algorithms have emerged as effective tools for addressing state-of-health issues by learning hard-to-model electrochemical properties from data. This paper presents a data-driven method for quantifying battery degradation modes. Ninety-one statistical features are extracted from the incremental capacity curve derived from 1/3C charging data. These features are then screened based on dispersion, contribution, and correlation. Subsequently, machine learning models, including four baseline algorithms and a feedforward neural network, are used to estimate the degradation modes. Experimental validation indicates that the feedforward neural network outperforms the others, achieving a root mean square error of around 10\% across all three degradation modes (i.e., loss of lithium inventory, loss of active material on the positive electrode, and loss of active material on the negative electrode). The findings in this paper demonstrate the potential of machine learning for diagnosing battery degradation modes in charging station scenarios.

Improving Low-Fidelity Models of Li-ion Batteries via Hybrid Sparse Identification of Nonlinear Dynamics

Accurate modeling of lithium ion (li-ion) batteries is essential for enhancing the safety, and efficiency of electric vehicles and renewable energy systems. This paper presents a data-inspired approach for improving the fidelity of reduced-order li-ion battery models. The proposed method combines a Genetic Algorithm with Sequentially Thresholded Ridge Regression (GA-STRidge) to identify and compensate for discrepancies between a low-fidelity model (LFM) and data generated either from testing or a high-fidelity model (HFM). The hybrid model, combining physics-based and data-driven methods, is tested across different driving cycles to demonstrate the ability to significantly reduce the voltage prediction error compared to the baseline LFM, while preserving computational efficiency. The model robustness is also evaluated under various operating conditions, showing low prediction errors and high Pearson correlation coefficients for terminal voltage in unseen environments.

Power-Efficient Actuation for Insect-Scale Autonomous Underwater Vehicles

We present a new evolution of the Very Little Eel-Inspired roBot, the VLEIBot++, a 900-mg swimmer driven by two 10-mg bare high-work density (HWD) actuators, whose functionality is based on the use of shape-memory alloy (SMA) wires. An actuator of this type consumes an average power of about 40 mW during in-air operation. We integrated onboard power and computation into the VLEIBot++ using a custom-built printed circuit board (PCB) and an 11-mAh 3.7-V 507-mg single-cell lithium-ion (Li-Ion) battery, which in conjunction enable autonomous swimming for about 20 min on a single charge. This robot can swim at speeds of up to 18.7 mm/s (0.46 Bl/s) and is the first subgram microswimmer with onboard power, actuation, and computation developed to date. Unfortunately, the approach employed to actuate VLEIBot++ prototypes is infeasible for underwater applications because a typical 10-mg bare SMA-based microactuator requires an average power on the order of 800 mW when operating underwater. To address this issue, we introduce a new 13-mg power-efficient high-performance SMA-based microactuator that can function with similar power requirements (approx. 80 mW on average) and actuation performance (approx. 3 mm at low frequencies) in air and water. This design is based on the use of a sealed flexible air-capsule that encloses the SMA wires that drive the microactuator with the purpose of passively controlling the heat-transfer rate of the thermal system. Furthermore, this new power-efficient encapsulated actuator requires low voltages of excitation (3 to 4 V) and simple power electronics to function. The breakthroughs presented in this paper represent a path towards the creation of insect-scale autonomous underwater vehicles (AUVs).

SambaMixer: State of Health Prediction of Li-ion Batteries using Mamba State Space Models

The state of health (SOH) of a Li-ion battery is a critical parameter that determines the remaining capacity and the remaining lifetime of the battery. In this paper, we propose SambaMixer a novel structured state space model (SSM) for predicting the state of health of Li-ion batteries. The proposed SSM is based on the MambaMixer architecture, which is designed to handle multi-variate time signals. We evaluate our model on the NASA battery discharge dataset and show that our model outperforms the state-of-the-art on this dataset. We further introduce a novel anchor-based resampling method which ensures time signals are of the expected length while also serving as augmentation technique. Finally, we condition prediction on the sample time and the cycle time difference using positional encodings to improve the performance of our model and to learn recuperation effects. Our results proof that our model is able to predict the SOH of Li-ion batteries with high accuracy and robustness.

Federated Automatic Latent Variable Selection in Multi-output Gaussian Processes

This paper explores a federated learning approach that automatically selects the number of latent processes in multi-output Gaussian processes (MGPs). The MGP has seen great success as a transfer learning tool when data is generated from multiple sources/units/entities. A common approach in MGPs to transfer knowledge across units involves gathering all data from each unit to a central server and extracting common independent latent processes to express each unit as a linear combination of the shared latent patterns. However, this approach poses key challenges in (i) determining the adequate number of latent processes and (ii) relying on centralized learning which leads to potential privacy risks and significant computational burdens on the central server. To address these issues, we propose a hierarchical model that places spike-and-slab priors on the coefficients of each latent process. These priors help automatically select only needed latent processes by shrinking the coefficients of unnecessary ones to zero. To estimate the model while avoiding the drawbacks of centralized learning, we propose a variational inference-based approach, that formulates model inference as an optimization problem compatible with federated settings. We then design a federated learning algorithm that allows units to jointly select and infer the common latent processes without sharing their data. We also discuss an efficient learning approach for a new unit within our proposed federated framework. Simulation and case studies on Li-ion battery degradation and air temperature data demonstrate the advantageous features of our proposed approach.

Generating multi-scale NMC particles with radial grain architectures using spatial stochastics and GANs

Understanding structure-property relationships of Li-ion battery cathodes is crucial for optimizing rate-performance and cycle-life resilience. However, correlating the morphology of cathode particles, such as in NMC811, and their inner grain architecture with electrode performance is challenging, particularly, due to the significant length-scale difference between grain and particle sizes. Experimentally, it is currently not feasible to image such a high number of particles with full granular detail to achieve representivity. A second challenge is that sufficiently high-resolution 3D imaging techniques remain expensive and are sparsely available at research institutions. To address these challenges, a stereological generative adversarial network (GAN)-based model fitting approach is presented that can generate representative 3D information from 2D data, enabling characterization of materials in 3D using cost-effective 2D data. Once calibrated, this multi-scale model is able to rapidly generate virtual cathode particles that are statistically similar to experimental data, and thus is suitable for virtual characterization and materials testing through numerical simulations. A large dataset of simulated particles with inner grain architecture has been made publicly available.

Long-term usage of the off-grid photovoltaic system with lithium-ion battery-based energy storage system on high mountains: A case study in Payiun Lodge on Mt. Jade in Taiwan

Energy supply on high mountains remains an open issue since grid connection is unavailable. In the past, diesel generators with lead-acid battery energy storage systems (ESSs) are applied in most cases. Recently, photovoltaic (PV) system with lithium-ion (Li-ion) battery ESS is an appropriate method for solving this problem in a greener way. In 2016, an off-grid PV system with Li-ion battery ESS has been installed in Paiyun Lodge on Mt. Jade (the highest lodge in Taiwan). After operation for more than 7 years, the aging problem of the whole electric power system becomes a critical issue for long-term usage. In this work, a method is established for analyzing the massive energy data (over 7 million rows) and estimating the health of the Li-ion battery system, such as daily operation patterns as well as C-rate, temperature, and accumulated energy distributions. The accomplished electric power improvement project dealing with the power system aging is reported. Based on the long-term usage experience, a simple cost analysis model between lead-acid and Li-ion battery systems is built, explaining that the expensive Li-ion batteries can compete with the cheap lead-acid batteries for long-term usage on high mountains. This case study provides engineers and researchers a fundamental understanding of the long-term usage of off-grid PV ESSs and engineering on high mountains.

The State of Lithium-Ion Battery Health Prognostics in the CPS Era

Lithium-ion batteries (Li-ion) have revolutionized energy storage technology, becoming integral to our daily lives by powering a diverse range of devices and applications. Their high energy density, fast power response, recyclability, and mobility advantages have made them the preferred choice for numerous sectors. This paper explores the seamless integration of Prognostics and Health Management within batteries, presenting a multidisciplinary approach that enhances the reliability, safety, and performance of these powerhouses. Remaining useful life (RUL), a critical concept in prognostics, is examined in depth, emphasizing its role in predicting component failure before it occurs. The paper reviews various RUL prediction methods, from traditional models to cutting-edge data-driven techniques. Furthermore, it highlights the paradigm shift toward deep learning architectures within the field of Li-ion battery health prognostics, elucidating the pivotal role of deep learning in addressing battery system complexities. Practical applications of PHM across industries are also explored, offering readers insights into real-world implementations.This paper serves as a comprehensive guide, catering to both researchers and practitioners in the field of Li-ion battery PHM.

GPT4Battery: An LLM-driven Framework for Adaptive State of Health Estimation of Raw Li-ion Batteries

State of health (SOH) is a crucial indicator for assessing the degradation level of batteries that cannot be measured directly but requires estimation. Accurate SOH estimation enhances detection, control, and feedback for Li-ion batteries, allowing for safe and efficient energy management and guiding the development of new-generation batteries. Despite the significant progress in data-driven SOH estimation, the time and resource-consuming degradation experiments for generating lifelong training data pose a challenge in establishing one large model capable of handling diverse types of Li-ion batteries, e.g., cross-chemistry, cross-manufacturer, and cross-capacity. Hence, this paper utilizes the strong generalization capability of large language model (LLM) to proposes a novel framework for adaptable SOH estimation across diverse batteries. To match the real scenario where unlabeled data sequentially arrives in use with distribution shifts, the proposed model is modified by a test-time training technique to ensure estimation accuracy even at the battery's end of life. The validation results demonstrate that the proposed framework achieves state-of-the-art accuracy on four widely recognized datasets collected from 62 batteries. Furthermore, we analyze the theoretical challenges of cross-battery estimation and provide a quantitative explanation of the effectiveness of our method.